4.7 Article

Graphene/β-MnO2composites-synthesis and its electroanalytical properties study in the Mg storage battery

Journal

INTERNATIONAL JOURNAL OF ENERGY RESEARCH
Volume 44, Issue 13, Pages 10238-10250

Publisher

WILEY
DOI: 10.1002/er.5644

Keywords

cathode materials; graphene; graphite; ionic liquid; magnesium battery; manganese dioxide

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Graphene/beta-MnO(2)composites were synthesized via ultrasonication method, followed by calcination at 400 degrees C for 4 hours. The structural properties of synthesized graphene and graphene/beta-MnO(2)composites were systematically studied using different instruments, such as XRD, FESEM, TEM, EDX, XPS and FT-IR spectroscopy. Furthermore, magnesium storage performance was scientifically studied using various electroanalytical characterizations like galvanostatic charge/discharge, electrochemical impedance spectra and cyclic voltammetry. The GNS/beta-MnO2-20% composite displays the discharge capacity of 110 mAh/g within 60 cycles at a current density of 25 mA/g, which is an excellent rate capability, and magnesium storage performance around 100 cycles. There is a significant improvement in electrochemical properties of GNS/beta-MnO2-20% composite materials as cathode for magnesium storage system due to the synergetic interaction between a pure beta-MnO(2)particle and graphene sheet.

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