Journal
INORGANICA CHIMICA ACTA
Volume 508, Issue -, Pages -Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ica.2020.119637
Keywords
Pyrazolone; Epoxidation; Transition metal complexes; Cyclooctene; Crystal structure
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Funding
- Czech Science Foundation [18-10504S, CZ.2.16/3.1.00/24510]
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A series of transition metal complexes of 4-acetyl-3-methyl-1-phenyl-2-pyrazoline-5-one with Ni(II), Cu(II), Fe (III) and Mn (II) central metal ions have been synthesized and characterized by X-ray crystallography, UV-Vis and FTIR spectroscopy, and elemental analysis. The complexes were used as a catalyst for epoxidation of cyclooctene with tert-butylhydroperoxide. Various parameters, including catalyst type and amount, solvent type and amount, oxidant/substrate ratio and time, have been optimized. The highest catalytic activity was found for Cu(II) complex at the optimized conditions. Very high selectivity for the epoxide product (cyclooctene oxide) was also obtained.
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