Journal
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Volume 2020, Issue 29, Pages 2769-2790Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.202000409
Keywords
Pincer ligands; Metallylenes; Germylenes; Stannylenes; Group 14 elements
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Funding
- Centre National de la Recherche Scientifique (CNRS)
- Babes-Bolyai University of Cluj-Napoca
- Ministry of Research and Innovation, CNCS - UEFISCDI within PNCDI III [PN-III-P4-ID-PCE-2016-0351]
- Universite de Toulouse (UPS)
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Pincer ligands have an important role in stabilizing group 14 metallylenes. The particular structure of the aryl pincer ligands makes them a unique ligand platform. This review is focused on presenting monoanionic metallylenes stabilized by aryl pincer-type ligands, described so far in the literature, with focus on their synthesis, structural features, and reactivity. Throughout this work, the close correlation between structure and reactivity is highlighted, as well as the manner in which this influences the stability of the compounds and their potential applications.
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