Optimization of SO2 and NOx sequential wet absorption in a two-stage bioscrubber for elemental sulphur valorisation

Flue gases contain SO(2)and NO(x)that can be treated together for elemental sulphur recovery in bioscrubbers, a technology that couples physical-chemical and biological processes for gaseous emissions treatment in a more economic manner than classical absorption. Sequential wet absorption of SO(2)and NO(x)from flue gas is thoroughly studied in this work in a two-stage bioscrubber towards elemental sulphur valorisation pursuing reuse of biological process effluents as absorbents. The optimal operating conditions required for SO(2)and NO(x)absorption in two consecutive spray absorbers were defined using NaOH-based absorbents. Overall, removal efficiencies of 98.9% and 55.9% for SO(2)and NO(x)abatement were obtained in two in-series scrubbers operated under a gas contact time of 1 and 100 s, and a liquid-to-gas ratio of 7.5 and 15 L m(-3), respectively. Higher NO(x)removal efficiency to clean gas emission was obtained by oxidants dosing in the absorber for NO(x)absorption. High NaHCO(3)concentration in a two-stage bioscrubber effluent was exploited as alkaline absorbent for flue gas treatment. The performance of scrubbers using an absorbent mimicking a reused effluent exhibited the same removal efficiencies than those observed using NaOH solutions. In addition, the reuse of bioprocess effluent reduced reagents' consumption by a 63.7%. Thus, the two-stage bioscrubber proposed herein offers an environmentally friendly and economic alternative for flue gas treatment.

Automated summary

This study investigated the sequential wet absorption of SO(2) and NO(x) in a two-stage bioscrubber using NaOH-based absorbents. The results showed high removal efficiencies for both SO(2) and NO(x) under specific operating conditions, with the option of using oxidants for improved NO(x) removal. The reuse of bioprocess effluent as an absorbent showed promising results in terms of removal efficiencies and reduced reagents' consumption.