Journal
DYES AND PIGMENTS
Volume 177, Issue -, Pages -Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.dyepig.2020.108275
Keywords
BODIPY; Functionalization; C-H amination; TD-DFT calculations
Funding
- National Natural Science Foundation of China [21801057, 21871072]
- Research funding project of Hangzhou Normal University [2018PYXML009, 2018QDL002, 2018YLXK16]
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A facile and direct C-H amination reaction at the 3-positions of BODIPY core was proceeded with high regioselectivity upon treatment with various amines. Spectroscopic properties of the 3-aminoBODIPY were substantially modulated by electron-donating nitrogen atoms. Theoretical calculations had been used to analyze the structure-property relationships and could be well explained for the regioselectivity of amination.
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