Journal
COMPOSITE INTERFACES
Volume 28, Issue 5, Pages 511-525Publisher
TAYLOR & FRANCIS LTD
DOI: 10.1080/09276440.2020.1792630
Keywords
PLLA; carbon nanotube; in vitro degradation; mechanical properties; thermal properties
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Funding
- University of The Basque Center [EHU10/12]
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The addition of nanotubes significantly improved the mechanical properties and conductivity of the scaffolds, with an optimal nanotube weight percentage of 1% to 5% resulting in the best properties. High levels of nanotubes (10%) led to the formation of aggregates, showing that the production techniques used were not suitable for such high reinforcement levels. The degradation process of the scaffolds was influenced by morphology, rather than crystallinity, and the addition of nanotubes changed the dielectric properties of the samples from insulator to conductor.
Poly(L-lactide (PLLA), nano-hydroxyapatite (nHA) and multi-walled carbon nanotube (MWCNTs) biodegradable scaffolds were produced through thermally induced phase separation (TIPS) and ultrasonically dispersed for use in tissue engineering. The results obtained showed that mechanical properties and conductivity improved with respect to the PLLA to which nanotubes had been added. Scaffolds with a nanotube weight of 1% and 5% showed the best properties, with a very uniform and well-arranged structure. The weight percentage of nanotubes is an essential parameter in determining the formation of agglomerates. Samples with a 10% carbon nanotube (CNT) weight showed aggregates, with the TIPS and ultra-sonication techniques found to be unsuitable for production with such high levels of reinforcement. The degradation process was modulated by morphology and not crystallinity, with the PLLA/nHA samples degrading more readily due to their smaller pores which did not allow degradation products to escape as easily, resulting in autocatalytic degradation. The addition of nanotubes had a significant impact on the dielectric properties of the samples, which ceased to be an insulator and became a conductor.
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