Journal
CHIRALITY
Volume 32, Issue 11, Pages 1311-1323Publisher
WILEY
DOI: 10.1002/chir.23275
Keywords
catalytic dualism; enantiodivergent catalysis; H-bonding ligands
Funding
- Macquarie University [2015071]
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Trifunctional MAP-based chiral phosphines were tested as new ligands in a Pd-catalyzed asymmetric allylic alkylation, demonstrating fast and enantiodivergent catalysis. The palladium complexes of representative ligands by X-ray analysis revealed a novel mode ofP,N-coordination of the ligand to the palladium center, which may contribute to switching the sense of the asymmetric induction via combined steric and tunable H-bonding interactions between the metal complex and the substrates.
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