Journal
CHINESE JOURNAL OF CHEMISTRY
Volume 38, Issue 12, Pages 1565-1570Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cjoc.202000216
Keywords
1,3-Dipolar cycloaddition; Principal interacting orbital; Metal carbyne complex; Azide
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Funding
- Research Grants Council of Hong Kong [N_HKUST603/15]
- NSFC [21561162001]
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A Summary of main observation and conclusion 1,3-Dipolar cycloaddition reaction between organic azide and metal carbyne is a useful strategy to construct metallacycles. However, the electronic behavior of organic azide in 1,3-dipolar cycloaddition reactions is less explored. This work revealed the unexpected role of organic azide as electrophiles in its cycloadditions with various metal carbynes. The feasibility and regioselectivity of a Fischer-type osmium carbyne in its reaction with an organic azide are explained by the increased nucleophilicity of carbyne carbon upon bending.
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