Journal
CHEMPHYSCHEM
Volume 21, Issue 17, Pages 1951-1956Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cphc.202000445
Keywords
alcohols; hydroxyl groups; metal-organic frameworks; molecular mobility; solid-state NMR spectroscopy
Funding
- y Russian Foundation for Basic Research [18-29-04009]
- Ministry of Science and Higher Education of the Russian Federation [AAAA-A17-117041710084-2]
Ask authors/readers for more resources
We present a detailed solid-state NMR characterization of the molecular dynamics oftert-butyl alcohol (TBA) confined inside breathing metal-organic framework (MOF) MIL-53(Al).Al-27 MAS NMR has demonstrated that TBA adsorption induces the iX phase of MIL-53 material with partially shrunk channels.H-2 solid-state NMR has shown that the adsorbed alcohol exhibits anisotropic rotations of the methyl groups around twoC3axes and librations of the molecule as a whole about the axis passing through the TBA C-O bond. These librations are realized by two distinct ways: fast molecule orientation change during the translational jump diffusion along the channel with characteristic time tau(D)of about 10(-9) s at 300 K; slow local librations at a single coordination site, representing framework hydroxyl groups, with tau(l)approximate to 10(-6) s at 300 K. Self-diffusion coefficient of the alcohol in the MOF has been estimated:D=3.4x10(-10) m(2) s(-1)at 300 K. It has been inferred that both the framework flexibility and the interaction with framework hydroxyl groups define the dynamics of TBA confined in the channels of MIL-53 (Al).
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available