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Tuning the Oxidation States of Dopants: A Strategy for the Modulation of Material Photoluminescence Properties

Journal

CHEMISTRY-A EUROPEAN JOURNAL
Volume 27, Issue 3, Pages 905-914

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.202003074

Keywords

charge balance; dopant valence state; doped materials; luminescent materials

Funding

  1. National Agency for Research (ANR Young Researchers) [ANR-16-CE08-0003-01]

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Doped single-phase materials are widely studied due to their easy synthesis and diverse properties. Tuning the oxidation states of dopants opens up possibilities for optimizing specific properties for various applications. Techniques for quantifying each valence state of dopant and high throughput methods are crucial for the discovery of efficient materials with dopants in multiple valence states.
Doped single-phase materials have been widely investigated owing to their easy to implement synthesis and the variety of their properties. This Minireview covers strategies for the co-stabilization and the ratio control of several oxidation states of dopants inserted in the same host. The tuning of the oxidation states of dopants opens up many possibilities for the optimization of specific properties and can be envisioned for various applications such as telecommunication, medicine, displays, lasers or lighting. Technics used for the quantification of each valence state of dopant are also emphasized, and the importance of high throughput methods for the discovery of efficient materials with dopants in multiple valence states is discussed.

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