Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 26, Issue 53, Pages 12134-12139Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.202002150
Keywords
covalent organic frameworks; heterogeneous catalysts; olefin hydroformylation; triphenylphosphine
Categories
Funding
- National Natural Science Foundation of China (NSFC) [21773107]
- Netherlands Organization for Scientific Research (NWO) [731.016.401]
Ask authors/readers for more resources
The synthesis of phosphine-based functional covalent organic frameworks (COFs) has attracted great attention recently. Herein, we present two examples of triphenylphosphine-based COFs (termed P-COFs) with well-defined crystalline structures, high specific surface areas, and good thermal stability. Furthermore, rhodium catalysts with these P-COFs as support material show high turnover frequency for the hydroformylation of olefins, as well as excellent recycling performance. This work not only extends the phosphine-based COF family, but also demonstrates their application in immobilizing homogeneous metal-based (e.g., Rh-phosphine) catalysts for application in heterogeneous catalysis.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available