Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 26, Issue 69, Pages 16286-16290Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.202002322
Keywords
flow chemistry; nanoparticles; spin crossover; supercritical CO2
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Funding
- University of Bordeaux
- CNRS
- ANR FlowSwitch [2019-CE07-0022-01]
- Region Nouvelle Aquitaine
- ADEME agency through the ISOCEL project
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Switchable materials are increasingly considered for implementation in devices or multifunctional composites leading to a strong need in terms of reliable synthetic productions of well-defined objects. Here, an innovative and robust template-free continuous process was developed to synthesize nanoparticles of a switchable coordination polymer, including the use of supercritical CO2, aiming at both quenching the particle growth and drying the powder. This all-in-one process offers a 12-fold size reduction in a few minutes while maintaining the switching properties of the selected spin crossover coordination polymer.
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