4.6 Review

Photoredox Organic Synthesis Employing Heterogeneous Photocatalysts with Emphasis on Halide Perovskite

Journal

CHEMISTRY-A EUROPEAN JOURNAL
Volume 26, Issue 58, Pages 13118-13136

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.202002145

Keywords

catalysis; metal halide perovskites; photocatalysis; photoredox organic synthesis; synthesis design

Funding

  1. NSF under the Chemical Catalysis program [1851747]
  2. Center for Hybrid Organic Inorganic Semiconductors for Energy (CHOISE) an Energy Frontier Research Center - Office of Science, Office of Basic Energy Sciences within the US Department of Energy
  3. Division Of Chemistry
  4. Direct For Mathematical & Physical Scien [1851747] Funding Source: National Science Foundation

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Lately, heterogeneous semiconductor materials have been explored as an emerging type of efficient photocatalyst for photoredox organic synthesis. Among these semiconductors, lead halide perovskite materials demonstrate unique properties towards excellent charge separation and charge transfer, extremely long charge carrier migration, high efficiency in visible light absorption, and long excited states lifetimes, etc., as proved in ground-breaking solar cell applications, garnering necessary merits for an efficient catalytic system for photoredox organic reactions. Here, the latest progress in heterogeneous semiconductor materials towards this endeavor is examined, with particular emphasis on lead halide perovskite nanocrystals (NCs) in photocatalytic organic synthesis.

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