4.6 Review

Multifunctional Features of Organic Charge-Transfer Complexes: Advances and Perspectives

Journal

CHEMISTRY-A EUROPEAN JOURNAL
Volume 27, Issue 2, Pages 464-490

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.202002640

Keywords

charge-transfer complexes; electrical functionalities; multicomponent supramolecules; optical properties; stimuli-response

Funding

  1. National Natural Science Foundation of China [21602113, 61774087]
  2. Research Foundation for Advanced Talents of Nanjing University of Posts & Telecommunications
  3. Jiangsu Specially Appointed Professor Foundation
  4. AcRF Tier 1, Singapore [RG 111/17, RG 2/17, RG 114/16, RG 8/16]
  5. AcRF Tier 2, Singapore [MOE 2017-T2-1-021, MOE 2018-T2-1-070]
  6. 111 Project [D20015]
  7. State Key Laboratory of Supramolecular Structure and Materials, Jilin University [sklssm2020041]

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Charge-transfer complexes have shown promising applications in various fields, with multicomponent CTCs emerging as ideal organic active semiconductors due to their superior performance and stability compared to single components. Recent research has focused on the development of different CTCs and their performance in various devices and behaviors.
The recent progress of charge-transfer complexes (CTCs) for application in many fields, such as charge transport, light emission, nonlinear optics, photoelectric conversion, and external stimuli response, makes them promising candidates for practical utility in pharmaceuticals, electronics, photonics, luminescence, sensors, molecular electronics and so on. Multicomponent CTCs have been gradually designed and prepared as novel organic active semiconductors with ideal performance and stability compared to single components. In this review, we mainly focus on the recently reported development of various charge-transfer complexes and their performance in field-effect transistors, light-emitting devices, lasers, sensors, and stimuli-responsive behaviors.

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