4.6 Article

Crystal structure and admirable luminescence properties of novel red emitting BiOCl: Eu3+ phosphors for indoor illumination

Journal

CHEMICAL PHYSICS LETTERS
Volume 752, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.cplett.2020.137599

Keywords

w-LEDs; Red phosphors; Luminescent performance; Rare-earth ions

Funding

  1. National Nature Science Foundation of China [51808533]
  2. National Key Research and Development Program of China [2016YFC0400806]
  3. Science and Technology Major Product of the Bureau of Science and Technology of Xiamen [3502Z20191012]

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The BiOCl: Eu3+ phosphors were synthesized, utilizing a solid-state reaction method. The crystal structure and morphology of the Eu3+-doped BiOCl were elucidated. The Eu3+-activated BiOCl phosphors showed broad adsorption in the near-ultraviolet region, which emitted intense red emission with the color purity of 71.8%. The quantum yield of the Bi0.95OCl: 0.05Eu(3+) phosphor was found to be 0.323. Moreover, the recorded temperaturedependent luminescence spectra indicate that the emission intensity at 150 degrees C could still remain 80% of that at room temperature, which also verified an excellent thermal resistance performance for the Bi0.95OCl: 0.05Eu(3+) sample, which have great potential for indoor illumination.

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