Journal
CERAMICS INTERNATIONAL
Volume 46, Issue 11, Pages 17614-17620Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2020.04.063
Keywords
Surface treatment; High thermal conductivity; Surface analysis
Categories
Funding
- Chung-Ang University Graduate Research Scholarship in 2019
- National Research Foundation of Korea (NRF) - Korea government (MSIT) [2017R1A2A2A05069858]
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Thermal conductivity of boron nitride is extremely anisotropic. To solve this problem, aggregate boron nitride (A-BN) was fabricated using binder. However, it is easily broken by external forces and has poor wettability. In this study, a new substance that overcomes these issues was introduced. Its coating material was prepared through a hydrolysis and condensation reaction involving polysilazane (PSZ) and (3-glycidyloxypropyl)tri-methoxysilane (GPTMS); The PSZ protected the shape of the A-BN and the GPTMS enhances its wettability. After solving these inherent problems of A-BN, the thermal conductivity was 7.014 W/m*K at a filler fraction of 50 vol %, which was 50 times higher than that of a neat epoxy composite.
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