Journal
CARBON
Volume 164, Issue -, Pages 198-206Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.carbon.2020.03.054
Keywords
Nickel; Oxygen; Graphene; Scanning tunneling microscopy
Funding
- Russian Foundation for Basic Research (RFBR) [16-29-06426]
Ask authors/readers for more resources
This paper reports an STM study of all stages of the intercalation of oxygen at the interface of a strongly coupled graphene/Ni(111) system prepared by temperature programmed growth (TPG) method. We have found that at the first stage of the intercalation at 120 degrees C, oxygen forms a chemisorbed layer on Ni(111) with a coverage about 0.26-0.28 ML, approximately described by the compressed p(2 x 2) lattice. The second stage of the intercalation is the formation of a single NiO(100) layer visualized in STM images as a specific 'square' superstructure at the graphene/Ni(111) interface. It was also established that the rate of the oxygen intercalation at 250 degrees C is much higher than at 120 degrees C. After intercalation at 250 degrees C, STM also reveals the formation of regions with 'free-standing' graphene, associated with the presence of a double nickel oxide layer underneath. (C) 2020 Elsevier Ltd. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available