Journal
CHINESE PHYSICS LETTERS
Volume 33, Issue 8, Pages -Publisher
IOP PUBLISHING LTD
DOI: 10.1088/0256-307X/33/8/085201
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Funding
- National High-Technology Research and Development Program of China [2014AA06A513, 2013AA065502]
- National Natural Science Foundation of China [61378041]
- Anhui Province Outstanding Youth Science Fund of China [1508085JGD02]
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Due to its complicated matrix effects, rapid quantitative analysis of chromium in agricultural soils is difficult without the concentration gradient samples by laser-induced breakdown spectroscopy. To improve the analysis speed and accuracy, two calibration models are built with the support vector machine method: one considering the whole spectra and the other based on the segmental spectra input. Considering the results of the multiple linear regression analysis, three segmental spectra are chosen as the input variables of the support vector regression (SVR) model. Compared with the results of the SVR model with the whole spectra input, the relative standard error of prediction is reduced from 3.18% to 2.61% and the running time is saved due to the decrease in the number of input variables, showing the robustness in rapid soil analysis without the concentration gradient samples.
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