Journal
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING
Volume 126, Issue 7, Pages -Publisher
SPRINGER HEIDELBERG
DOI: 10.1007/s00339-020-03692-2
Keywords
Nanoferrites; Autocombustion; Rietveld; Infrared; Magnetic properties; Cation distribution
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Unprecedented analysis of the impact of high-level Al(3+)substitution on the structural and magnetic properties of low-coercivity Co0.5Zn0.5AlxFe2-xO4(0.3 <= x <= 0.8) nanoferrites prepared via autocombustion method is presented. Single-phase cubic structure has been assured for all samples using XRD patterns and FTIR spectra. Due to the notable difference in the ionic radii of Fe(3+)and Al3+, structural defects are created for high substitution levels, which is to be balanced by cation redistribution and/or the appearance of Fe(2+)and Co(3+)cations. Rietveld analysis and size-strain plots were used to explain the non-monotonic change of the lattice parameter, microstrain and crystallite size. For the as-prepared samples, the estimated size ranged from 9 to 19 nm, which was confirmed by HRTEM images. Magnetic properties were deduced fromM-Hloops traced at room temperature. Saturation magnetization (M-S) decreased with increasing Al(3+)content while coercivity (H-c) was fluctuating. Based on the experimental data of XRD, FTIR, and VSM, a cation distribution has been proposed and tightly correlated with the structural and magnetic properties. The significant reduction of the lattice parameter and coercivity for the sample withx = 0.8 upon sintering process has been explained in the light of the cation distribution.
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