Journal
APPLIED CATALYSIS B-ENVIRONMENTAL
Volume 267, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.apcatb.2020.118670
Keywords
Doping; Co3O4 nanoparticles; Holey nanosheets; Intrinsic activity; Soot combustion
Funding
- National Natural Science Foundation of China [21276214]
- Fujian Province Natural Science Foundation [2015J05033]
- Fundamental Research Funds for the Central Universities [20720170043]
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Cobalt-based catalysts were synthesized through the evolution of Co3O4 nanoparticles into holey nanosheets. The holey Co-Ce oxide nanosheets were found to have the highest activity and stability for soot combustion at loose contact mode as a result of the successful doping of trace amount of Ce ions in Co3O4, which improves the intrinsic activity. Additionally, better solid-solid contact was also achieved on holey Co-Ce oxide nanosheets because of the mesoporous structure and large external surface formed. The catalytic mechanism was investigated with in-situ Raman spectra, which indicated that the superoxide species and O-2(delta-) (0 < delta < 1) species had reacted with soot preferentially, and the weakly bonded oxygen species had a low temperature activity even in the absence of O-2. Overall, this study indicated that the two-dimensional (2D) holey Co-Ce nanosheets exhibited superior catalytic performance for soot combustion, which is of great significance for future applications.
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