Journal
APPLIED CATALYSIS A-GENERAL
Volume 602, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.apcata.2020.117678
Keywords
Lean methane mitigation; catalytic combustion; Pd/H-ZSM-5; alkali metal; deposition-precipitation; Pd dispersion
Categories
Funding
- National Key R&D Program of China [2018YFB0604804]
- Strategic Program of Coal-based Technology of Shanxi Province of China [MQ2014-11, MQ2014-10]
- National Natural Science Foundation of China [21991092, 21773281, 21802157, U1862101]
- Strategic Priority Research Program of the Chinese Academy of Sciences [XDA21020500]
- CAS/SAFEA International Partnership Program for Creative Research Teams
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A series of alkali metal hydroxides (MeOH, Me = Li, Na, K and Cs) were used as the precipitant to prepare the Pd/H-ZSM-5-Me catalysts by deposition-precipitation; the effect of alkali metal cations on the catalytic performance of Pd/H-ZSM-5 in the combustion of lean methane was then investigated. The results indicate that in comparison with ammonia, alkali metal hydroxides as the precipitant can greatly enhance the catalytic performance of Pd/H-ZSM-5 in lean methane combustion and the extent of promoting effect follows the order of CsOH > KOH > NaOH > LiOH> > NH4OH. The alkali metal cations can enhance the dispersion of Pd on the H-ZSM-5 support and effectively reduce the size of Pd particles; in addition, the alkali metal cations may serve as an electron-donating component and endow the Pd species with a unique electronic characteristic, which can promote the activation of C-H bond of methane molecules.
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