Journal
CHINESE JOURNAL OF ORGANIC CHEMISTRY
Volume 36, Issue 3, Pages 512-519Publisher
SCIENCE PRESS
DOI: 10.6023/cjoc204509001
Keywords
oleanolic acid; Baeyer-Villiger reaction; lactone
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Funding
- Open-Fund Program of the State Key Laboratory of Natural and Biomimetic Drugs [K20150214]
- Scientific Research Foundation of Kunming University of Science and Technology [KKSY201560002]
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Oleanolic acid (OA), a naturally occurring triterpene, was found to have a variety of biological and pharmacological properties. To expand its structural diversity, a series of oleanolic acid derivatives, including ring A and/or ring C expansion, were performed via Baeyer-Villiger reaction using m-CPBA and urea-hydrogen peroxide. The structures of all products were characterized by H-1 NMR, C-13 NMR and HRMS.
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