4.8 Review

Dual Emission: Classes, Mechanisms, and Conditions

Journal

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 60, Issue 42, Pages 22624-22638

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.202009789

Keywords

dual emission; energy transfer; fluorescence; phosphorescence; photoswitches

Funding

  1. Spanish Ministerio de Economia y Competitividad (MINECO-FEDER) [CTQ2017-87054, SEV-2016-0686]
  2. Campus of International Excellence (CEI) UAM+CSIC
  3. Basic Science Research Program through the NRF - Ministry of Science, ICT, and Future Planning [2017R1E1A1A01075372]
  4. National Research Foundation of Korea [2017R1E1A1A01075372] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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The passage discusses the growing interest in dual-emission materials for materials and life science applications, highlighting the lack of a systematic overview of the underlying processes. It classifies dual-emission phenomena and describes relevant mechanisms for materials science, while also providing references for further reading and inspiration for future designs of dual-emission materials.
There has been much interest in dual-emission materials in the past few years for materials and life science applications; however, a systematic overview of the underlying processes is so-far missing. We resolve this issue herein by classifying dual-emission (DE) phenomena as relying on one emitter with two emitting states (DE1), two independent emitters (DE2), or two correlated emitters (DE3). Relevant DE mechanisms for materials science are then briefly described together with the electronic and/or geometrical conditions under which they occur. For further reading, references are given that offer detailed insight into the complex mechanistic aspects of the various DE processes or provide overviews on materials families or their applications. By avoiding ambiguities and misinterpretations, this systematic, insightful Review might inspire future targeted designs of DE materials.

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