4.8 Review

Photocatalysis Enhanced by External Fields

Journal

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 60, Issue 30, Pages 16309-16328

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.202009518

Keywords

charge separation; external fields; photocatalysis; semiconductors

Funding

  1. National Natural Science Foundation of China [51972288, 51672258]
  2. Fundamental Research Funds for the Central Universities [2652018287]

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The efficient conversion of solar energy through photocatalysis has great potential to address the energy crisis and environmental pollution. However, unsatisfactory conversion efficiency remains a challenge. Introducing external fields can significantly enhance the photocatalytic performance of semiconductors, leading to various applications.
The efficient conversion of solar energy by means of photocatalysis shows huge potential to relieve the ongoing energy crisis and increasing environmental pollution. However, unsatisfactory conversion efficiency still hinders its practical application. The introduction of external fields can remarkably enhance the photocatalytic performance of semiconductors from the inside out. This review focuses on recent advances in the application of diverse external fields, including microwaves, mechanical stress, temperature gradient, electric field, magnetic field, and coupled fields, to boost photocatalytic reactions, for applications in, for example, contaminant degradation, water splitting, CO2 reduction, and bacterial inactivation. The relevant reinforcement mechanisms of photoabsorption, the transport and separation of photoinduced charges, and adsorption of reagents by the external fields are highlighted. Finally, the challenges and outlook for the development of external-field-enhanced photocatalysis are presented.

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