4.8 Review

Metal Halide Perovskite Nanocrystals in Metal-Organic Framework Host: Not Merely Enhanced Stability

Journal

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 60, Issue 14, Pages 7488-7501

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.202006169

Keywords

encapsulation; host materials; metal-organic frameworks; nanocrystals; perovskite

Funding

  1. National Key Research and Development Program [2017YFE0127100]
  2. National Key R&D Program of China [2018YFC1800600]
  3. Shanghai Sailing Program [19YF1422200]
  4. Guangdong Province's 2018-2019 Key RD Program [2019B010924001]

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Perovskite nanocrystals exhibit excellent optoelectronic properties but suffer from poor stability, which can be enhanced by encapsulating them within multifunctional metal-organic frameworks. Researchers have discussed the synthesis strategies, functional mechanisms, and applications of perovskite NC@MOF composites.
As an emerging optical material, perovskite nanocrystals (NCs) exhibit excellent optoelectronic properties and show great potential for various optoelectronic applications. However, the inherent inferior stability against moisture, oxygen, light and heat limit their practical application. As well, the exploration and development of perovskite NCs with novel properties and functions are new challenges. To achieve these goals, the integration and encapsulation of perovskite NCs with multifunctional metal-organic frameworks (MOFs) to form perovskite NC@MOF composites, is a promising strategy for enhancing the stability and broadening the application scope. In this minireview, we summarize and discuss the synthesis strategies and functional mechanisms of perovskite NC@MOF composites, along with applications of light emitting diodes (LED), information security, photocatalysis, sensing, and detection. We further briefly point out the current challenges as well as the future opportunities for the emerged composite materials.

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