Static and dynamic behavior of magnetic particles at fluid interfaces

This perspective work reviews the current status of research on magnetic particles at fluid interfaces. The article gives both a unified overview of recent experimental advances and theoretical studies centered on very different phenomena that share a common characteristic: they involve adsorbed magnetic particles that range in size from a few nanometers to several millimeters. Because of their capability of being remotely piloted through controllable external fields, magnetic particles have proven essential as building blocks in the design of new techniques, smart materials and micromachines, with new tunable properties and prospective applications in engineering and biotechnology. Once adsorbed at a fluid-fluid interfase, in a process that can be facilitated via the application of magnetic field gradients, these particles often result sorely confined to two dimensions (2D). In this configuration, inter-particle forces directed along the perpendicular to the interface are typically very small compared to the surface forces. Hence, the confinement and symmetry breaking introduced by the presence of the surface play an important role on the response of the system to the application of an external field. In monolayers of particles where the magnetic is predominant interaction, the states reached are strongly determined by the mode and orientation of the applied field, which promote different patterns and processes. Furthermore, they can reproduce some of the dynamic assemblies displayed in bulk or form new ones, that take advantage of the interfacial phenomena or of the symmetry breaking introduce by the confining boundary. Magnetic colloids are also widely used for unraveling the guiding principles of 2D dynamic self-assembly, in designs devised for producing interface transport, as tiny probes for assessing interfacial rheological properties, neglecting the bulk and inertia contributions, as well as actuated stabilizing agents in foams and emulsions. (C) 2020 Elsevier B.V. All rights reserved.