Journal
ADVANCED MATERIALS
Volume 32, Issue 34, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201907098
Keywords
heterostructured TiO2-Fe2O3; hierarchical structures; Li-O(2)batteries; low overpotential; photo-assistance
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Funding
- National Natural Science Foundation of China [21621001, 21835002, 51771177, 51972141]
- 111 Project of China [B17020]
- Education Department of Jilin Province [JJKH20190113KJ]
- Jilin Province Science and Technology Development Program [20190303104SF]
- Jilin Province/Jilin University Co-construction Project-Funds for New Materials [SXGJSF2017-3]
- National Postdoctoral Program for Innovative Talents [BX20180119]
- China Postdoctoral Science Foundation [2019M651194]
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Photo-assisted charging is considered an effective approach to reducing the overpotential in lithium-oxygen (Li-O-2) batteries. However, the utilization of photoenergy during the discharge process in a Li-O(2)system has been rarely reported, and the functional mechanism of such a process remains unclear. Herein, a novel bifunctional photo-assisted Li-O(2)system is established by employing a hierarchical TiO2-Fe(2)O(3)heterojunction, in which the photo-generated electrons and holes play key roles in reducing the overpotential in the discharging and charging processes, respectively. Moreover, the morphology of the discharge product (Li2O2) can be modified via the dense surface electrons of the cathode under illumination, resulting in promoted decomposition kinetics of Li(2)O(2)during the charging progress. Accordingly, the output and input energies of the battery can be tuned by illumination, giving an ultralow overpotential of 0.19 V between the charge and discharge plateaus with excellent cyclic stability (retaining a round-trip efficiency of approximate to 86% after 100 cycles). The investigation of the bifunctional photo-assisted process presented here provides significant insight into the mechanism of the photo-assisted Li-O(2)battery and addresses the overpotential bottleneck in this system.
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