Journal
CHINESE CHEMICAL LETTERS
Volume 27, Issue 7, Pages 1017-1021Publisher
ELSEVIER SCIENCE INC
DOI: 10.1016/j.cclet.2016.04.021
Keywords
Pillar[6]arene; Photocyclodimerization; Anthracenecarboxylic acid; Supramolecular complexation
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Funding
- National Natural Science Foundation of China [21372165, 21321061, 21572142, 21402129]
- State Key Laboratory of Polymer Materials Engineering [sklpme2014-2-06]
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The complexation behaviors of anthracenecarboxylic acid and water-soluble cationic pillararenes have been investigated by H-1 NMR, UV-vis and ITC methods. The cationic pillar[6]arene was found to stepwise form 1:1 and 1:2 complexes, having a large K-1 and a relatively small K-2 values. Photocyclodimerization of AC within the pillar[6]arene improved the yield of the head-to-head photodimers. Up to 4.97 HH/HT ratio has been reached by optimizing the reaction conditions. (C) 2016 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.
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