Journal
ACS APPLIED MATERIALS & INTERFACES
Volume 12, Issue 25, Pages 28700-28710Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsami.0c07405
Keywords
phase change material; fire safety; thermal regulation; thermal energy storage; supramolecular self-assembly
Funding
- National Key R&D Program of China [2019YFD1101201]
- National Natural Science Foundation of China [51827803, 51991351]
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The leakage and fire hazard of organic solid-liquid phase change material (PCM) tremendously limit its long-term and safe application in thermal energy storage and regulation. In this work, novel nanoflake-fabricated organic-inorganic supramolecular hierarchical microspheres denoted as BPL were synthesized through the electrostatically driven assembly of poly(ethylene ammonium phenylphosphamide) (BP) decorated layered double hydroxides using sodium dodecyl sulfate as a template. Then the BPL was simultaneously utilized as a porous supporting material and flame retardant for polyethylene glycol to fabricate shape-stabilized PCM (BS-PCM). Benefiting from the structural uniqueness of the BPL microsphere, the BS-PCM possessed a high latent heat capacity of 116.7 J g(-1) and excellent thermoregulatory capability. Moreover, the BS-PCM had no apparent leakage after a 200-cycle heating/cooling process and showed excellent thermal reversibility, superior to similar solid-liquid PCMs reported in recent literature. More interestingly, unlike flammable PEG, BS-PCM showed excellent fire resistance when exposed to a fire source. The unique BPL porous microsphere provided not only a microcontainer with high storage capacity for solid-liquid PCM, but also a fire resistant barrier to PEG, supplying a promising solution for highly efficient and fire-safe thermal energy storage.
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