Journal
ACS APPLIED MATERIALS & INTERFACES
Volume 12, Issue 28, Pages 31896-31903Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsami.0c05921
Keywords
redox nanosheet; liquid/liquid interfacial technique; electrochromism; transparent; cyclic stability
Funding
- CREST project of the Japan Science and Technology (JST) agency [JPMJCR1533]
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Highly dense hexagonal Fe(II)-based coordination nanosheets (CONASHs) were designed by dual-branching, at the metal-coordination moieties and the tritopic ligands, which successfully obtained a liquid/liquid interface by the complexation of Fe(II) ions and the tritopic bidentate ligands. The 1:1 complexation was confirmed by titration. The obtained Fe(II)-based nanosheets were fully characterized by small-angle X-ray scattering (SAXS), atomic force microscopy (AFM), scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), and X-ray photoelectron spectroscopy (XPS). A monolayer of the sheets was obtained, employing the Langmuir-Blodgett (LB) method, and the determined thickness was similar to 2.5 nm. The polymer nanosheets exhibited red-to-colorless electrochromism because the electrochemical redox transformation between Fe(II) and Fe (III) ions controlled the appearance/disappearance of the metal (ion)-to-ligand charge-transfer (MLCT) absorption. The poor pi-conjugation in the tritopic ligands contributed to the highly colorless electrochromic state. A solid-state device, with the robust polymer film, exhibited excellent electrochromic (EC) properties, with high optical contrast (Delta T > 65%) and high durability after repeated color changes for >15 000 cycles, upon applying low-operating voltages (+1.5/0 V).
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