Journal
ACS OMEGA
Volume 5, Issue 20, Pages 11655-11670Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsomega.0c00951
Keywords
-
Categories
Funding
- NSFC [21801191, 21572163, 21873074]
- Wenzhou Science & Technology Bureau [G20180016]
- College Students Innovation and Entrepreneurship Training Program [JWSC2018079]
- Laboratory open project of Wenzhou University [JW19SK65]
Ask authors/readers for more resources
An efficient method to access (E)-trisubstituted alkenes is reported via cobalt-catalyzed isomerization of 1,1-disubstituted alkenes using a phosphine-amido-oxazoline ligand. The reaction could also convert mono- and 1,2-disubstituted alkenes to (E)-internal alkenes with benzylic selectivity. This protocol is atom-economy and operationally simple and uses readily available starting materials with good functional tolerance. This catalytic system could be scaled up to gram scale smoothly with a catalyst loading of 0.1 mol %.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available