Journal
MOLECULAR CATALYSIS
Volume 487, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.mcat.2020.110889
Keywords
Nickel nitride; Furfuryl alcohol; Hydrogenation; Furfural; Biorefinery
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Funding
- Spanish Ministry of Innovation, Science and Universities [RTI2018094918-B-C44]
- FEDER (European Union) funds
- University of Malaga
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A series of C-rich nickel nitride nanoparticles supported on silica has been prepared by the urea glass route, with urea as nitrogen and carbon source, and characterized by different physico-chemical techniques. They consist of Ni3N nanoparticles of 20-25 nm embedded into a carbonaceous matrix. These catalysts are much more active and stable than a nickel supported silica catalyst, which drastically deactivates. The supported Ni3N catalyst with a 10 wt.% Ni maintained a furfural conversion higher than 80 % after 5 h of time-on-stream, at 170 degrees C, with a high WHSV of 6 h(-1). Complete initial furfural conversion values were observed at reaction temperatures varying from 170 to 230 degrees C, and the selectivity toward furan and furfuryl alcohol (decarbonylation and hydrogenation products, respectively) was tuned by varying this temperature. After the catalytic tests, XPS and XRD have demonstrated that nanoparticles are stable, although carbonaceous deposits were also detected.
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