Journal
MOLECULAR CATALYSIS
Volume 485, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.mcat.2020.110820
Keywords
Three-dimensionally ordered honeycomb-; shaped catalyst; CuO-doped Mn2O3; CO oxidation; Hydrothermal stability
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Funding
- Iran Science Elites Federation
- Iran National Science Foundation [97017638]
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Highly 3D ordered honeycomb-shaped xCuO center dot Mn2O3 (CuO content (x) = 10, 20, and 30 wt%) catalysts with various CuO contents were synthesized by adopting a colloidal crystal template method with poly(methyl methacrylate) (PMMA) as template, and the as-prepared catalysts were used in oxidation of CO. The catalysts possessed a macro-mesoporous structure. The catalytic performance at low temperatures improved significantly with a rise in CuO content. The light-off temperature (10 % conversion) and the temperature for CO complete conversion were 71 and 98 degrees C over 30 wt% CuO center dot Mn2O3, respectively. Good stability of the 30 wt% CuO center dot Mn2O3 catalyst was also observed under the dry and wet (in the presence of water vapor) conditions. It is concluded that high catalytic activity of 30 wt.% CuO center dot Mn2O3 was related to its unique pore structure, high oxygen adspecies concentration, and oxygen vacancy.
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