4.5 Article

Upgrading of biomass pellets by torrefaction and its influence on the hydrophobicity, mechanical property, and fuel quality

Journal

BIOMASS CONVERSION AND BIOREFINERY
Volume 12, Issue 6, Pages 2061-2070

Publisher

SPRINGER HEIDELBERG
DOI: 10.1007/s13399-020-00666-5

Keywords

Biomass pellets; Torrefaction; Soybean straw; Pine wood; Mechanical properties; Hydrophobicity

Funding

  1. CAS Key Laboratory of Renewable Energy [Y907k31001]
  2. National Natural Science Foundation of China [51776100]
  3. Six Talent Peaks Project of Jiangsu Province [XNY-027]
  4. 333 Project of Jiangsu Province [BRA2019270]
  5. Qinglan Project of Jiangsu Province

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This study investigates the effect of torrefaction temperature on the physicochemical properties, hydrophobicity, and mechanical properties of soybean straw pellets and pine wood pellets. The results show that torrefaction leads to the disappearance of certain oxygen-containing functional groups and a significant decrease in oxygen content in the pellets. The equilibrium moisture content and hydrophobicity are affected by the torrefaction temperature. Furthermore, as the temperature increases, the mechanical properties of the pellets decrease.
In this study, soybean straw pellets (SSP) and pine wood pellets (PWP) were used as materials for torrefaction at 200-350 degrees C. Impacts of torrefaction temperature on the physicochemical properties, hydrophobicity, and mechanical properties of the pellets were investigated. Results showed that some oxygen-containing functional groups in the biomass pellets disappeared during torrefaction, and the oxygen content significantly decreased. The hydrophobic behavior of biomass is highly affected by their chemical composition. A significant decrease in hemicellulose content was observed in torrefied pellets. Consequently, the equilibrium moisture content of torrefied pellets decreased significantly; and the torrefied PWP remained intact even after immersion of more than 2 h in water. As the torrefaction temperature increased, the cellulose and lignin started to decompose and formed more micropores. Meanwhile, the torrefied pellets became less dense, which lowered the mechanical properties of the pellets. Optimal temperature for the preparation of high-quality torrefied SSP and torrefied PWP was found to be 250 degrees C and 300 degrees C, respectively, since higher temperatures cause excessive loss of volatiles and degradation of mechanical properties without significantly enhancing the high heating value of torrefied pellets.

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