Journal
CHEMISTRYSELECT
Volume 5, Issue 15, Pages 4548-4551Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/slct.202000642
Keywords
arylmethyl chloride; benzoselenazoles; chloronitrobenzene; redox condensation; selenium powder
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Funding
- Jiangsu Synergetic Innovation Center for Advanced BioManufacture [XTC1806]
- National Natural Science Foundation of China [21676142]
- Science and Technology Planning Project of Nanjing [201716035]
- Six Talent Peaks Project in Jiangsu Province [SWYY-030/SWYY-118]
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A selenium-mediated redox condensation of 2-chloronitrobenzene and arylmethyl chloride to obtain 2-arylbenzoselenazoles has been realized under metal-free condition. The reactions proceeded in moderate-to-good yields with good functional compatibility and gram-scale achievement. Primarily mechanistic investigation suggested that key intermediate Bn(Se)nBn II, was first isolated and confirmed by NMR.
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