Journal
ACS SENSORS
Volume 5, Issue 5, Pages 1474-1481Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acssensors.0c00495
Keywords
covalent organic frameworks; in situ film growth; capacitive gas sensing; benzene detection; sub-ppm level
Funding
- National Research Foundation Singapore [NRF2018-NRF-ANR007 POCEMON]
- Ministry of Education-Singapore (MOE AcRF Tier 1) [R-279-000-540-114]
- Ministry of Education-Singapore (MOE AcRF Tier 2) [MOE2018-T2-2-148, MOE2019-T2-1-093]
- Agency for Science, Technology and Research [IRG A1783c0015, IAF-PP A1789a0024]
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State-of-the-art chemical sensors based on covalent organic frameworks (COFs) are restricted to the transduction mechanism relying on luminescence quenching and/or enhancement. Herein, we present an alternative methodology via a combination of in situ-grown COF films with interdigitated electrodes utilized for capacitive benzene detection. The resultant COF-based sensors exhibit highly sensitive and selective detection at room temperature toward benzene vapor over carbon dioxide, methane, and propane. Their benzene detection limit can reach 340 ppb, slightly inferior to those of the metal oxide semiconductor-based sensors, but with reduced power consumption and increased selectivity. Such a sensing behavior can be attributed to the large dielectric constant of the benzene molecule, distinctive adsorptivity of the chosen COF toward benzene, and structural distortion induced by the custom-made interaction pair, which is corroborated by sorption measurements and density functional theory (DFT) calculations. This study provides new perspectives for fabricating COF-based sensors with specific functionality targeted for selective gas detection.
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