4.6 Article

Hexnuclear Cadmium(II) Cluster Constructed from Tris(2-methylpyridyl)amine (TPA) and Azides

Journal

CRYSTALS
Volume 10, Issue 4, Pages -

Publisher

MDPI
DOI: 10.3390/cryst10040317

Keywords

cadmium; bridged azide; poylnuclear; cluster; X-ray; luminescence emission

Funding

  1. Department of Chemistry -University of Louisiana at Lafayette

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A novel rare hexa nuclear cadmium(II)-azide cluster, [Cd-6(TPA)(4)(mu(3)-1,1,3-N-3)(4)(mu(2)-1,1-N-3)(6)](ClO4)(2)2H(2)O (1) was isolated and structurally characterized, in which the azide ligands reveal mu-1,1,3- and mu-1,1-N-3 bridging modes.

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