Journal
CHEMSUSCHEM
Volume 10, Issue 2, Pages 455-460Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cssc.201601270
Keywords
biomass; cellulose; deep eutectic solvent; green chemistry; methyl carbamate
Funding
- Kone Foundation
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This study presents the use of a reactive deep eutectic solvent (DES) for the chemical modification of wood cellulose fibers. DES based on dimethylurea and ZnCl2 was used to synthetize cellulose methyl carbamate (CMeC). This synthesis was performed at elevated temperature under solvent-free conditions. Chemical characterization based on FTIR and NMR indicated that methyl carbamate was successfully introduced to cellulose, and a degree of substitution (DS) of 0.17 was obtained after 3 h of reaction at 150 degrees C. The product with a DS of 0.17 exhibited good alkaline solubility (in 3% NaOH solution) after freeze-thawing, whereas the original cellulose fibers were practically insoluble even in 9% NaOH. As dimethylurea can be produced from CO2, this method can be used as a sustainable way to obtain novel cellulose materials with desirable properties for use in a wide range of applications.
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