Journal
CHEMSUSCHEM
Volume 9, Issue 3, Pages 246-251Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cssc.201501376
Keywords
carbon dioxide fixation; doping; hydrogen; palladium; supported catalysts
Funding
- National Natural Science Foundation of China [21403218, 21476226, 21503125, 21506204]
- CAS [KGZD-EW-T05]
- DICP Fundamental Research Program for Clean Energy [DICPM201307]
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The lack of safe, efficient, and economical hydrogen storage technologies is a hindrance to the realization of the hydrogen economy. Reported herein is a reversible formate-based carbon-neutral hydrogen storage system that is established over a novel catalyst comprising palladium nanoparticles supported on nitrogen-doped mesoporous carbon. The support was fabricated by a hard template method and nitridated under a flow of ammonia. Detailed analyses demonstrate that this bicarbonate/formate redox equilibrium is promoted by the cooperative role of the doped nitrogen functionalities and the well-dispersed, electron-enriched palladium nanoparticles.
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