Journal
CHEMPHYSCHEM
Volume 17, Issue 9, Pages 1224-1251Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cphc.201600104
Keywords
chemical reaction dynamics; femtosecond stimulated Raman spectroscopy; time-resolved vibrational spectroscopy; ultrafast spectroscopy; visual photochemistry
Funding
- Mathies Royalty Fund
- German Research Foundation (DFG) [DI1998/1-1]
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Femtosecond stimulated Raman spectroscopy (FSRS) is an ultrafast nonlinear optical technique that provides vibrational structural information with high temporal (sub-50fs) precision and high spectral (10cm(-1)) resolution. Since the first full demonstration of its capabilities approximate to 15years ago, FSRS has evolved into a mature technique, giving deep insights into chemical and biochemical reaction dynamics that would be inaccessible with any other technique. It is now being routinely applied to virtually all possible photochemical reactions and systems spanning from single molecules in solution to thin films, bulk crystals and macromolecular proteins. This review starts with an historic overview and discusses the theoretical and experimental concepts behind this technology. Emphasis is put on the current state-of-the-art experimental realization and several variations of FSRS that have been developed. The unique capabilities of FSRS are illustrated through a comprehensive presentation of experiments to date followed by prospects.
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