Journal
CHEMPHYSCHEM
Volume 17, Issue 6, Pages 812-816Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cphc.201501136
Keywords
chemical shift anisotropy; heavy spin 1/2 nuclei; magic angle spinning; NMR spectroscopy; tin
Funding
- Max Planck Society
- Deutsche Forschungsgemeinschaft
- NSERC of Canada
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The benefits of the ultrafast magic-angle spinning (MAS) approach for the acquisition of ultrawide-line NMR spectraspectral simplification, increased mass sensitivity allowing the fast study of small amounts of material, efficient excitation, and application to multiple heavy nucleiare demonstrated for tin(II) oxide (SnO) and the tin complex [(LB)(SnCl)-Cl-II](+)[(SnCl3)-Cl-II](-) [LB=2,6-diacetylpyridinebis(2,6-diisopropylanil)] containing two distinct tin environments. The ultrafast MAS experiments provide optimal conditions for the extraction of the chemical-shift anisotropy tensor parameters, anisotropy, and asymmetry for heavy spin-1/2 nuclei.
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