Journal
CHEMISTRYOPEN
Volume 9, Issue 8, Pages 806-811Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/open.202000053
Keywords
amination reactions; energetic materials; heterocycles; N-amines; primary explosives
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Funding
- Army Research Office (ARO) [W911NF-18-1-0463]
- Purdue University
- Office of Naval Research (ONR)
- National Science Foundation [CHE 1625543]
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Energetic N-amino-C-nitro compounds 1-amino-4-nitro-1,2,3-triazole and 2-amino-4-nitro-1,2,3-triazole are characterized for the first time as energetic materials. These compounds were characterized chemically by nuclear magnetic resonance (NMR), Infrared spectroscopy and X-ray crystallography. Compounds were also characterized energetically by differential scanning calorimetry (DSC), impact, and friction and found to possess sensitivities and performances classifying them as primary explosives with PETN-like performance.
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