Journal
ASIAN JOURNAL OF ORGANIC CHEMISTRY
Volume 9, Issue 5, Pages 753-756Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ajoc.202000121
Keywords
ruthenium; transfer hydrogenation; desymme-trization; 1; 3-cyclopentanediones; (+)-estrone
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Funding
- National Natural Science Foundation of China [21871255]
- Strategic Priority Program of Chinese Academy of Sciences [XDB17020300]
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A facile synthesis of chiral cis beta-hydroxy ketones was successfully developed through ruthenium-catalyzed transfer hydrogenative desymmetrization of 1,3-cyclopentanedione. The experiment on gram scale could be performed without loss of reactivity and enantioselectivity.
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