Journal
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
Volume 8, Issue 20, Pages 7569-7573Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acssuschemeng.0c02223
Keywords
Mechanochemistry; Ball milling; Nanographenes; Planarization; Cyclodehydrogenation
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Funding
- Federal Ministry of Education and Research (Bundesministerium fur Bildung and Forschung, BMBF) Mechanocarb project [03SF0498]
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Elemental copper can be utilized to generate C-C bonds in order to synthesize nanographenes in a mechanochemical environment. Utilizing the solvent-free environment of a ball mill, we present a facile and highly sustainable concept for the internal C-C coupling in oligo-phenyls on the example of triphenylene and extend it to the transformation of hexaphenylbenzene into hexa-peri-hexabenzocoronene as a benchmark nanographene.
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