Journal
CHEMOSPHERE
Volume 144, Issue -, Pages 855-863Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.chemosphere.2015.09.054
Keywords
Dielectric barrier discharge plasma; Activated carbon fibers; Triclosan; Modification; Intermediates; Degradation pathway
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Funding
- National Science and Technology Major Project on Water Pollution Control and Treatment [2014ZX07204-008]
- National Natural Science Foundation of China [51208163]
- State Key Laboratory of Hydrology-Water Resources and Hydraulic Engineering, Hohai University [2013491211]
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The degradation of triclosan (TCS) in aqueous solution by dielectric barrier discharge (DBD) plasma with activated carbon fibers (ACFs) was investigated. In this study, ACFs and DBD plasma coexisted in a planar DBD plasma reactor, which could synchronously achieve degradation of TCS, modification and in situ regeneration of ACFs, enhancing the effect of recycling of ACFs. The properties of ACFs before and after modification by DBD plasma were characterized by BET and XPS. Various processing parameters affecting the synergetic degradation of TCS were also investigated. The results exhibited excellent synergetic effects in DBD plasma-ACFs system on TCS degradation. The degradation efficiency of 120 mL TCS with initial concentration of 10 mg L-1 could reach 93% with 1 mm thick ACFs in 18 min at input power of 80 W, compared with 85% by single DBD plasma. Meanwhile, the removal rate of total organic carbon increased from 12% at pH 6.26-24% at pH 3.50. ACFs could ameliorate the degradation efficiency for planar DBD plasma when treating TCS solution at high flow rates or at low initial concentrations. A possible degradation pathway of TCS was investigated according to the detected intermediates, which were identified by liquid chromatography-hybrid quadrupole time-of-flight mass spectrometry (LC-QTOE-MS) combined with theoretical calculation of Gaussian 09 program. (C) 2015 Elsevier Ltd. All rights reserved.
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