Journal
POLYMERS
Volume 12, Issue 3, Pages -Publisher
MDPI
DOI: 10.3390/polym12030616
Keywords
SBS rubber; nano-carbon black; cold plasma; polymer surface modification; adhesion; bound rubber
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Funding
- Polish National Centre for Research and Development (NCBiR) [PBS3/A5/51/2015]
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Studies on the surface modification of commercial styrene-butadiene-styrene (SBS) rubber with different carbon black (CB) nanofiller content (10-80 parts per hundred parts of rubber (phr)) performed by low-pressure oxygen plasma are presented in this paper. The adhesion properties of the rubber were determined by the peel test for adhesive-bonded joints prepared with a water-based polyurethane (PU) adhesive. The chemical structure and morphology of the SBS rubber surface before and after plasma treatment were investigated by X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM), respectively. The peel tests showed that the plasma treatment significantly improved the strength of adhesive-bonded joints in the entire range of CB tested, revealing a clear maximum for approximately 50 phr of CB. It was also found that as a result of plasma treatment, functional groups that are responsible for the reactions with the PU adhesive, such as C-OH and C=O, were formed, and their concentration, similar to the peel strength, showed maximum values for approximately 50 phr CB. The occurrence of these maxima was explained using the bound rubber model.
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