Journal
Chemistry-An Asian Journal
Volume 11, Issue 22, Pages 3148-3158Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.201601170
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Funding
- Ministry of Economy and Competitiveness (MINECO) of Spain
- Fondo Europeo de Desarrollo Regional [CTQ2015-70795-P/BQU]
- Consolider-Ingenio [CSD2010-00065]
- Catalan Department for Innovation, Universities and Enterprise (DIUE) of the Generalitat de Catalunya [2009SGR637]
- ICREA-Academia
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The development of catalysts for the selective oxidation of readily available hydrocarbons or organic precursors into oxygenated products is a long-standing goal in organic synthesis. In the last decade, some iron coordination complexes have shown the potential to fit this role. These catalysts can mimic the O-O activation mode of far more so-phisticated iron oxygenase enzymes, generating powerful yet selective oxidants. In this review, we report state-of-theart C-H and C=C oxidations catalyzed by non-heme iron complexes and H2O2 as the oxidant. Finally, we briefly describe some novel oxidative reactivity and the perspectives of this chemistry.
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