Experimental and numerical study on photocatalytic activity of the ZnO nanorods/CuO composite film

The photocatalytic activity of the ZnO NRs/CuO composite film was investigated by using both experimental and numerical methods. The ZnO NRs/CuO composite film exhibits significantly enlarge absorption range to visible-light and suppress the recombination rate of the photogenerated electron-hole pairs, which can be well utilized as a photocatalyst. The ZnO NRs/CuO composite film also presents good stability, and reusability, and durability for photo-decomposition purpose. The optimal ZnO NRs/CuO composite film contains 1 mu-thick of CuO film and 10 nm-thick of ZnO NRs film. The donor concentration in ZnO NRs film should be lower than 10(16)cm(-3). The short circuit current density of the optimal composite film is 25.8mA/cm(2) resulting in the calculated pseudo-order rate constant of 1.85s(-1). The enhancement in degradation efficiency of this composite film is attributed to the inner electric field and large effective surface area of ZnO NRs film.