Journal
CHEMISTRY-AN ASIAN JOURNAL
Volume 11, Issue 13, Pages 1883-1886Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.201600563
Keywords
copper; nitrogen heterocycles; phenanthridines; silver; sodium
Categories
Funding
- Shanghai Pujiang Talent Program [11J1402500]
- National Natural Science Foundation of China [21171056]
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We have developed a Cu-II-, Ag-I-, and NaOTf-mediated intramolecular quaternization by arylation reactions to synthesize a variety of N-heterocyclic carbene (NHC) precursors with a benzene-fused backbone. The methodology also provides a convenient alternative route for the synthesis of 6-H-phenanthridine derivatives. A novel silver-NHC complex was prepared by treatment of Ag2O with the free carbene, which was in situ prepared from the deprotonation of a representative quinazolinonium salt.
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