Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 23, Issue 1, Pages 84-87Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201604943
Keywords
alkanes; boron; C-H activation; mechanism; ruthenium
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Funding
- European Research Council under the European Community's Seventh Framework Program (FP7 )/ERC [307535]
- COST program (CHAOS)
- Alexander von Humboldt foundation
- DAAD
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Versatile borylations of C(sp(2))-H and C(sp(3))-H were achieved with ruthenium(II) biscarboxylate complexes. The robust nature of the ruthenium(II) catalyst enabled C(sp(3))-H borylation on pyrrolidines, piperidines, and azepanes with ample scope and excellent positional selectivity control.
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